Windows - Review application whether 32-bit or 64bit

1. Way One

If you have a hex editor program, just open your file with it and shortly after the standard header intro stuff (like "This program cannot be run in DOS mode...") you will see either
"PE..L" (hex code: 504500004C) = 32 bit
or
"PE..d†" (hex code: 504500006486) = 64 bit

2. Way Two

dumpbin

This is  a tool which is included in vc package.

Run dumpbin in command line as followings.

dumpbin /HEADERS glslangValidator.exe

The outputs are as followings

Microsoft (R) COFF/PE Dumper Version 12.00.21005.1
Copyright (C) Microsoft Corporation.  All rights reserved.




Dump of file glslangValidator.exe


PE signature found


File Type: EXECUTABLE IMAGE


FILE HEADER VALUES
             14C machine (x86)
               5 number of sections
        578FF4EA time date stamp Thu Jul 21 06:02:18 2016
               0 file pointer to symbol table
               0 number of symbols
              E0 size of optional header
             102 characteristics
                   Executable
                   32 bit word machine